Laboratorio de Calidad de Alimentos Suelos y Aguas- EEA Pergamino, INTA. Av. Frondizi (Ruta 32) Km 4,5 (2700),
Pergamino, Provincia de Buenos Aires, Argentina
Some of the products generated by the Maillard reaction are desired and very important for defining consumer acceptance of breakfast cereals. However, in recent years there has been an increased concern about compounds that are potentially harmful such as furfurals. The aim of this work was to analyze the effectiveness of protein hydrolysis with pronase as a pretreament for the evaluation of furfurals generated by the Maillard reaction during toasting of cornflakes and the parallel development of brown and fluorescent compounds. Furfurals were more accurately quantified with the pronase hydrolysis pretreatment because the protein matrix binds furfurals and fluorescent compounds. For control of the early reaction steps in the toasting process, the most sensitive parameter was fluorescence.
Abraham K, Guertler R, Berg K, Heinemeyer G, Lampen A, Appel K. Toxicology and risk assessment of 5-hydroxymethylfurfural in food. Molecular Nutrition & Food Research. 2011. p. 667–78.
2.
Acevedo N, Schebor C, Buera P. Non-enzymatic browning kinetics analysed through water-solids interactions and water mobility in dehydrated potato. Food Chemistry. 2008. p. 900–6.
3.
Akkan A, Özdemir Y, Ekiz H. Derivative spectrophotometric determination of 5-(hydroxymethyl)-2-furaldehyde (hmf) and furfural in locust bean extract. Food/Nahrung. 2001. p. 43–6.
4.
Ameur L, Trystram G, Birlouez-Aragon I. Accumulation of 5hydroxymethyl-2-furfural in cookies during the backing process: validation of an extraction method. Food Chemistry. 2006. p. 790–6.
5.
Ameur L, Mathieu O, Lalanne V, Trystram G, Birlouez-Aragon I. Comparison of the effects of sucrose and hexose on furfural formation and browning in cookies baked at different temperatures. Food Chemistry. 2007. p. 1407–16.
6.
Chavez-Servin J, Romeu-Nadal M, Castellote A, Lopez-Sabater M. Evolution of free mono-and di-saccharide content of milk-based formula powder during storage. Food Chemistry. 2006. p. 103–8.
7.
Delgado-Andrade C, Morales F, Seiquer I, Navarro P, M. Maillard reaction products profile and intake from spanish typical dishes. Food Research International. 2010. p. 1304–11.
8.
Delgado-Andrade C, Rufian-Henares J, Morales F. Study on fluorescence of maillard reaction compounds in breakfast cereals. Molecular Nutrition & Food Research. 2006. p. 799–804.
9.
Delgado-Andrade C, Rufian-Henares J, Morales F. Optimised procedure to analyse maillard reaction-associated fluorescence in cereal-based products. Czech Journal of Food Sciences. 2008. p. 339–46.
10.
Fallico B, Zappala M, Arena E, Verzera A. Effects of conditioning on hmf content in unifloral honeys. Food Chemistry. 2004. p. 305–13.
11.
Farroni A, Del Pilar Buera M. Colour and surface fluorescence development and their relationship with mail lard reaction IJFS April. 2012. p. 95–105.
12.
Pronase aided extraction of Furfurals 105 markers as influenced by structural changes during cornflakes production. Food Chemistry. p. 1685–91.
13.
Fast R. Breakfast cereals and how they are made. American Association of Cereal Chemist; 2000. p. 17–54.
14.
Francis F, Clydesdale F. Food colorimetry: theory and applications. AVI Publishing Co. Inc; 1975.
15.
Gokmen V, Senyuva H. Improved method for the determination of hydroxymethylfurfural in baby foods using liquid chromatography-mass spectrometry. Journal of Agricultural and Food Chemistry. 2006. p. 2845–9.
16.
Gu FL, Kim J, Abbas S, Zhang XM, Xia SQ, Chen ZX. Structure and antioxidant activity of high molecular weight maillard reaction products from casein-glucose. Food Chemistry. 2010. p. 505–11.
17.
Matiacevich S, Buera M. A critical evaluation of fluorescence as a potential marker for the maillard reaction. Food Chemistry. 2006. p. 423–30.
18.
Morales F, Jimenez-Perez S. Hydroxymethylfurfural determination in infant milk-based formulas by micellar electrokinetic capillary chromatography. Food Chemistry. 2001. p. 525–31.
19.
Oral R, Dogan M, Sarioglu K, Toker O. 5-hydroxymethyl furfural formation and reaction kinetics of different pekmez samples: effect of temperature and storage. International Journal of Food Engineering. 2012.
20.
Oral R, Mortas M, Dogan M, Sarioglu K, Yazici F. New approaches to determination of hmf. Food Chemistry. 2014. p. 367–70.
21.
Palombo R, Gertler A, Saguy I. A simplified method for determination of browning in dairy powders. Journal of Food Science. 1984.
22.
Rada-Mendoza M, Sanz M, Olano A, Villamiel M. Formation of hydroxymethylfurfural and furosine during the storage of jams and fruit-based infant foods. Food Chemistry. 2004. p. 605–9.
23.
Ramirez-Jimenez A, Garcia-Villanova B, Guerra-Hernandez E. Hydroxymethylfurfural and methylfurfural content of selected bakery products. Food Research International. 2000. p. 833–8.
24.
Rehman Z, Saeed A, Zafar S. Hydroxymethylfurfural as an indicator for the detection of dried powder in liquid milk. Milchwissenschaft-milk Science International. 2000. p. 256–7.
25.
Rodríguez-Pulido F, Heredia F, Zaldívar-Cruz J, González-Miret M. Color in food. CRC Press; 2012. p. 113–20.
26.
Rufián-Henares J, Delgado-Andrade C, Morales F. Analysis of heatdamage indices in breakfast cereals: influence of composition. Journal of Cereal Science. 2006. p. 63–9.
27.
Soong Y, Tan S, Leong L, Henry J. Total antioxidant capacity and starch digestibility of muffins baked with rice, wheat, oat, corn and barley flour. Food Chemistry. 2014. p. 462–9.
28.
Tessier F, Birlouez-Aragon I. Health effects of dietary maillard reaction products: the results of icare and other studies. Amino Acids. 2012. p. 1119–31.
29.
Yam K, Papadakis S. A simple digital imaging method for measuring and analyzing color of food surfaces. Journal of Food Engineering. 2004. p. 95–105.
The statements, opinions and data contained in the journal are solely those of the individual authors and contributors and not of the publisher and the editor(s). We stay neutral with regard to jurisdictional claims in published maps and institutional affiliations.