This study evaluated the effectiveness of black rice, millet and barley bran extracts against oxidative degradation of sunflower oil in frying, by determining the total antioxidant activity, total phenolic content, free fatty acid content, conjugated diene content and total polar content. It was reported that the total phenolic content rice bran was approximately three times higher than that of the millet bran extracts and five times higher than the results for barley bran extracts. The total antioxidant activity results for barley bran and rice bran extract (40.95 ± 0.07and 40.87 ± 0.04 Trolox equivalent μmol/g of bran, respectively) were two times higher than that of millet bran extract (17.16 ± 0.34 Trolox equivalent μmol/g of bran). The results of the effectiveness of the cereal bran extracts were significantly different (p<0.05). The free fatty acid content of the rice bran and propyl gallate enriched oil samples showed better results (2.02 ± 0.01% and 1.62 ± 0.00%) than millet, barley and control enriched oil samples (3.43 ±0.01%, 3.13±0.01% and 6.13 ± 0.01% respectively). In the same vein, conjugated diene content results from all the enriched oil samples indicated that the rice bran enriched oil sample had the least amount of secondary oxidized products compared to the other enriched oil samples. It can be concluded that rice bran extract can be used for frying without discarding or replenishing the oil.

Date seeds are a major waste product of the date industry that could offer potentially valuable material for the production of useful food ingredients. The aim of the present study was to investigate the seeds of three date varieties of the UK market (Deglet Nour, Khouat Allig, and Zahidi) for their proximate composition, total phenolic (TPC), total flavonoid (TFC) contents and total antioxidant capacity (TAC) with a view to their eventual industrial application. Carbohydrates were present in the highest concentrations varying between 74.13 and 76.54 g 100 g-1 of date seed powder (DSP) on dry weight (DW) basis, followed in descending order by fats (7.64-8.84 g 100 g-1) and proteins (4.35-5.51 g 100 g-1). Potassium was found in high amounts with values ranging between 280.55 and 293.13 mg 100 g-1. The majority of the total phenolic content (2058-2984 mg GAE 100 g-1) was assumed to be composed of flavonoids (1271-1932 mg CAE 100 g-1). These families of dietary phenolics may be the major ones responsible for the high antioxidant capacity reported in date seeds, which varied from 12540 and 27699 µmol TE 100 g-1. These results suggest that date seeds can be considered a potential raw material for natural, active ingredients for food applications as well as an unexplored source of novel nutraceuticals and dietary supplements.